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A computer-assisted approach to the prediction of the primary structures of regular glycopolymers is described. The analysis is based on comparing the calculated 13 C NMR spectra of all the possible structures of the repeating unit (for the given monomeric composition) to an experimental 13 C NMR spectrum. The spectra generation is based on the spectral database containing...
The CASPER program which is used for determination of the primary structure of oligo- and polysaccharides has been extended. It can now handle a reduced number of experimental signals from an NMR spectrum in the comparison to the simulated spectra of structures that it generates, an improvement which is of practical importance since all signals in NMR spectra cannot always be identified. Furthermore,...
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