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NMR chemical shifts of d0 transition metal compounds show the following trends: (1) For single-bonded ligands such as M-H, M-CR3, M←NR3, M-SiR3 and M←PR3, 1H, 13C, 15N, 29Si and 31P shifts of these α atoms in the complexes of both first- and third-row transition metals are typically downfield from (or at higher frequencies than) those of second-row analogs with a “V-shape” (Trend 1). (2) For multiple-bonded...
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