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The structure and dynamics at the surface of nanoscopic hexadecane droplets immersed in aqueous phase with and without emulsifiers (1-alkanols of varying chain length; pentanol, heptanol, decanol and dodecanol) have been studied using atomistic molecular dynamics simulations. The nature of layering of alcohol molecules on the oil droplet is governed by the hydrophobicity of alkanols. Longer chain...
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