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Die regio‐ und enantioselektive, intermolekulare vicinale Fluoraminierung von α‐CF3‐Styrolen wurde durch enantioselektive II/IIII‐Katalyse erreicht. Unter Nutzung von C2‐symmetrischen, Resorcinol‐basierten Aryl Iodid‐Katalysatoren war es möglich, das kurzlebige Iodonium‐Zwischenprodukt mit einfachen Nitrilen abzufangen, die sowohl als Lösungsmittel als auch als Nucleophil fungieren. Die in situ Ritter‐Reaktion...
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