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Enthalpy of sublimation of solid compound can be found using the values of solution enthalpy and solvation enthalpy in any solvent. In this work enthalpies of solution at infinite dilution of a number of aromatic hydrocarbons derivatives in benzene were measured at 298.15K. Comparison between experimental and literature solution enthalpies in benzene at 298.15K and fusion enthalpies at melting temperature...
In this work a new solution-based calorimetry approach for determination of the sublimation and vaporization enthalpies of low volatile compounds was proposed. The approach is based on the measurement of solution enthalpy of a molecule of interest in benzene and as well as the measurement of molar refraction index for this molecule. Enthalpies of solution at infinite dilution in benzene for a set...
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