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The use of 1,1-diphenylethylenes in anionic polymerization is reviewed. The structure and reactivity of 1,1-diphenylethylenes and the corresponding simple and polymeric 1,1-diphenylalkyllithiums are described. The applications of 1,1-diphenylethylene chemistry include: 1.Their use to form initiators2.End-capping agents to attenuate reactivity for crossover to reactive, polar monomers or for functionalization...
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