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The theory of fluids near surfaces and in pores is reviewed and some simulations of electrolytes with a continuum solvent near an electrode that agree qualitatively with experiment but that are inexplicable by current theories are outlined. Recent work with more realistic solvents and membranes is discussed.
Ion current through individual pores in track-etched polyethyleneterephthalate filters can have the following properties which are shared by a number of biological ion channels:1) selectivity for cations over anions, or vice versa depending on the surface charge of the filter and the diameter of the pore;2) fluctuations between high- and low-conductance states;3) inhibition by protons and divalent...
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