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The adsorption and thermal decomposition of Mo(CO) 6 is reported on Ni{111}. At room temperature, Mo(CO) 6 has an extremely low sticking probability. At 450-550 K, Mo(CO) 6 adsorbs dissociatively via loss of one or more CO ligands to produce a surface intermediate stable up to about 675 K. Desorption of the remaining CO ligands leaves an essentially contaminant free NiMo surface...
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