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The adsorption and decomposition pathways of methanol on Al(111) at 90 K and 300 K have been studied using UPS, work function and thermal desorption spectroscopy measurements over a wide temperature range. Dissociative adsorption of methanol occurs at 90 K for low coverage (Θ<1/4 monolayer) to CH 3 O ads. and H and the chemisorbed intact methanol were found as the...
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