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The catalytic activity of the N‐tailed (“biuret”) TAML (tetraamido macrocyclic ligand) activators [Fe{4‐XC6H3‐1,2‐(NCOCMe2NCO)2NR}Cl]2− (3; N atoms in boldface are coordinated to the central iron atom; the same nomenclature is used in for compounds 1 and 2 below), [X, R=H, Me (a); NO2, Me (b); H, Ph (c)] in the oxidative bleaching of Orange II dye by H2O2 in aqueous solution is mechanistically compared...
“TAML activators” are full‐functional, small molecule peroxidase mimics that arguably outperform their enzyme progenitors (TAML=tetraamido macrocyclic ligand). In their Full Paper on page 6226 ff., S. S. Gupta, A. D. Ryabov, T. J. Collins et al. show that the Generation 5 (Gen‐5) TAML/H2O2 catalytic cycle follows the same path as Gen‐1 through Gen‐4. TAML reactivity in peroxide catalysis is subject...
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