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Photoresponsive binding kinetics was achieved in cucurbit[8]uril‐dithienylethene host‐guest complexes. This work demonstrates that, in the presence of a competitor guest (in purple), the host‐guest dissociation kinetics is approximately 100‐fold slower for the closed (green) than for the open (yellow) dithienylethene isomers (t 1/2=107 hours vs. t 1/2=1.2 hours), allowing control over the dissociation...
The use of external stimuli to control the binding kinetics in supramolecular systems is of critical importance for the development of advanced molecular machines and devices. In this work, a study focused on the kinetics of a water‐soluble host‐guest system based on cucurbit[8]uril and two dithienylethene (DTE) photoswitches is reported. It is shown that for the DTE guest comprising two anionic sulfonate...
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