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We present herein the synthesis of three new bis(corrolato‐ruthenium(III)) complexes containing unsupported Ru–Ru bonds and their characterization in different redox states. The 1H NMR spectra of the bis(corrolato‐ruthenium(III)) complexes displayed “normal” chemical shifts and the compounds proved to be EPR‐silent. Crystallographic characterization of the dimers indicated Ru–Ru distances of 2.175...
The diruthenium(III) compound [(μ‐oxa){Ru(acac)2}2] [1, oxa2−=oxamidato(2−), acac−=2,4‐pentanedionato] exhibits an S=1 ground state with antiferromagnetic spin‐spin coupling (J=−40 cm−1). The molecular structure in the crystal of 1⋅2 C7H8 revealed an intramolecular metal–metal distance of 5.433 Å and a notable asymmetry within the bridging ligand. Cyclic voltammetry and spectroelectrochemistry (EPR,...
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