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Quasi-single crystalline gold films of 20 nm thickness and preferential (111) orientation on Si hemispheres were modified by controlled potentiostatic deposition of Pd (sub-ML, ML, multi-L) from sulphate and/or chloride-containing electrolyte. The electrochemical properties of these model electrodes were characterised for hydrogen and (hydrogen-) sulphate adsorption as well as for surface oxide formation...
The potential dependence of the contact electroresistance (CER) of Ag, Au, Pt and Ir has been investigated in berate buffer solution (pH 9.4). The oxidation potentials of these metals were defined and the CER of its oxides were measured. The CER of Ir at pH 1-14 was shown to have anomalous low values. This made it possible to use Ir as the reference specimen (electrode) for measuring high CER values...
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