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The new piperideine alkaloid cicindeloine (3) was isolated from the pygidial glands of the beetles Stenus cicindeloides and Stenus solutus. The structure and absolute configuration of 3 were elucidated by NMR spectroscopy and asymmetric synthesis, respectively. A very efficient gram‐scale synthesis of 3 was developed using an intramolecular aza‐Wittig reaction as the final step. The synthetic route...
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