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The complexes Ag I (tripod)X with tripod=1,1,1-tris(diphenylphosphinomethyl)ethane and X − =Cl − and I − are luminescent in solution at r.t. It is suggested that the emission is a phosphorescence which originates from a tripod intraligand state for X=Cl (λ max =464nm) and a X − →tripod ligand-to-ligand charge transfer state for X=I (λ max =482...
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