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The complex [Ag(PPh3)4][(PPh3)CdCl3] was synthesized and its crystal structure was determined. Solid state properties of the complex were further studied by 31P SS-NMR, Raman and IR spectroscopies. This compound presents one of the rare cases of monomeric trichlorocadmate, the first reported with a phosphorus ligand. We can obtain this thanks to the use of a big spherical cation like [Ag(PPh3)4]+...
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