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Recent advances in the preparation and characterization of planar model catalysts and in ambient pressure surface spectroscopy enable us to investigate well-defined supported metal nanoparticles under working conditions, approaching the conditions of applied catalysis. The reactivity of Pd–Al 2 O 3 /NiAl(110) model catalysts for CO hydrogenation and methanol partial oxidation were...
The adsorption of O 2 on a monoatomic copper layer on Pd(111) leads to the formation of two distinctive copper oxide features which, in scanning tunneling microscopy (STM) images, appear in dark hexagonal form (A) and bright triangular form (B). By providing either the dark hexagonal or the bright triangular patches at a time, the chemical (oxidation) states of copper were studied by X-ray...
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