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The xenon–difluoronitrenium ion F2NXe+, a novel xenon–nitrogen species, was obtained in the gas phase by the nucleophilic displacement of HF from protonated NF3 by Xe. According to Møller–Plesset (MP2) and CCSD(T) theoretical calculations, the enthalpy and Gibbs energy changes (ΔH and ΔG) of this process are predicted to be −3 kcal mol−1. The conceivable alternative formation of the inserted isomers...
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