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Push‐pull substituted ruthenium(II) complexes strongly absorb green light and emit in the red to near‐infrared spectral region with a quantum yield of 1.3 % and a lifetime of the emissive triplet MLCT state of 477 ns. Amines reductively quench the long‐lived excited state enabling photoredox chemistry (light‐sensitized thiol‐ene click reaction) with green light. More information can be found in the...
Synthesis, characterization, electrochemistry, and photophysics of homo‐ and heteroleptic ruthenium(II) complexes [Ru(cpmp)2]2+ (22+) and [Ru(cpmp)(ddpd)]2+ (32+) bearing the tridentate ligands 6,2’’‐carboxypyridyl‐2,2’‐methylamine‐pyridyl‐pyridine (cpmp) and N,N’‐dimethyl‐N,N’‐dipyridin‐2‐ylpyridine‐2,6‐diamine (ddpd) are reported. The complexes possess one (32+) or two (22+) electron‐deficient dipyridyl...
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