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A ruthenium complex, KNa[Ru2(C6H6)2(CH3COO)6] (Ru‐KNa), and its polyoxotungstate derivative, Na6[{Ru(C6H6)}2W8O28(OH)2]·16H2O (Ru‐Na), have been successfully isolated from routine synthetic reactions and characterized by X‐ray single‐crystal structure analysis, IR spectroscopy and elemental analysis. A remarkable aspect of Ru‐KNa is that it has two ligand types, benzene and acetate, and the acetate...
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