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This work describes an experimental study of the effects of nitrogen and sulphur on the surface segregation of molybdenum in an Fe-3.5%Mo alloy. It is found that the presence of small concentrations of bulk dissolved nitrogen induce a strong synergetic segregation (cosegregation) of molybdenum and nitrogen. This effect is strongest for the (100)-oriented alloy, where an epitaxially stabilized MoN...
Molybdenum and nitrogen cosegregation is investigated on (100) oriented surfaces of Fe 3.5%Mo N single crystals applying Auger electron spectroscopy (AES) and low energy electron diffraction (LEED). The formation of a two-dimensional MoN surface compound occurs at temperatures ranging from 500 to 790°C. Ar + ion depth profiling indicates that the MoN consists of approximately two compound...
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