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Organic functional groups attract rare‐synthons from main group complexes as black holes do the matter from a star. No escape, no other ways. DFT‐calculations reveal that phosphasilenes can act as synthetic equivalents of highly reactive phosphinidene moieties. In the presence of properly tuned bulky groups, the usual reactivity of phosphasilenes towards unsaturated organic reactants is altered and...
We examine by the means of computational chemistry the ability of two phosphasilenes to transfer the phosphinidene moiety to four double bonded organic functional groups (>C=C<, ‐N=N‐, >C=O, and >C=S) in the presence of different bulky ligands. We show that large bulky groups in the reactants can sterically prohibit the otherwise favored association of reactants and phosphasilenes and...
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