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The known chemistry of the actinide series is dominated by that of uranium and thorium, but recent experimental and computational studies of the highly radioactive elements beyond uranium are bringing surprises and new insight in equal measure. Selected highlights from these developments are explored in this Minireview, with emphasis on contributions from computational quantum chemistry. For more...
Recent developments in the chemistry of the transuranic elements are surveyed, with particular emphasis on computational contributions. Examples are drawn from molecular coordination and organometallic chemistry, and from the study of extended solid systems. The role of the metal valence orbitals in covalent bonding is a particular focus, especially the consequences of the stabilization of the 5f...
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