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Transition‐metal‐catalyzed alkenylation of enolates provides a direct method to synthesize broadly useful β,γ‐unsaturated carbonyl compounds from the corresponding carbonyl compound and alkenyl halides. Despite being reported in the early seventies, this reaction class saw little development for many years. In the past decade, however, efforts to develop this reaction further have increased considerably,...
Dipalladium(I) and diruthenium(I) compounds bridged by two [{(5,7‐dimethyl‐1,8‐naphthyridin‐2‐yl)amino}carbonyl]ferrocene (L) ligands have been synthesized. The X‐ray structures of [Pd2L2][BF4]2 (1) and [Ru2L2(CO)4][BF4]2 (2) reveal dinuclear structures with short metal–metal distances. In both of these structures, naphthyridine bridges the dimetal unit, and the site trans to the metal–metal bond...
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