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Transition‐metal‐catalyzed copolymerization of olefins with polar monomers represents a challenge because of the large variety of substrate‐induced side reactions. However, this approach also holds the potential for the direct synthesis of polar functionalized polyolefins with unique properties. After decades of research, only a few catalyst systems have been found to be suitable for this reaction...
The ability to carry out transition‐metal‐catalyzed copolymerizations of olefins with polar monomers is a great challenge in the field of olefin polymerization. Palladium has been the dominant player in this field, while its low‐cost nickel counterpart has only achieved very limited success. We report the synthesis and evaluation of a highly versatile platform based on diphosphazane monoxide ligands...
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