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The substitution equilibrium between isocyanides and stanna‐closo‐dodecaborate with palladium(II) was investigated. The mixed substituted products of type [(RNC)2Pd(SnB11H11)2]2– and [(RNC)Pd(SnB11H11)3]4– were characterized by X‐ray crystal structure analysis, elemental analysis and NMR spectroscopy. Isocyanide insertion into palladium–carbon bonds was also found. The zwitterionic complexes isolated...
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