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Atropisomeric heterobiaryls have become a burgeoning research topic in synthetic and medicinal chemistry. Many catalytic enantioselective constructions of axially chiral heterobiaryls have been documented, and the strategy of ring formation has become a powerful tool toward this goal. In this Review, we summarize the atroposelective synthesis of N‐, O‐, and S‐containing heterobiaryls with five‐ or...
Atropisomeric heterobiaryls play a vital role in natural products, chiral ligands, organocatalysts, and other research fields, which have aroused great interest from chemists in recent years. Until now, a growing number of optically active heterobiaryls based on indole, quinoline, isoquinoline, pyridine, pyrrole, azole, and benzofuran skeletons have been successfully synthesized through metal or organic...
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