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Summary: Aqueous dispersions of diblock copolymer micelles with homogeneous hydrophobic core (polystyrene) and heterogeneous amphiphilic corona from ionic N‐ethyl‐4‐vinylpyridinium bromide (EVP) and hydrophobic 4‐vinylpyridine (4VP) units have been prepared at pH 9. The structure and dispersion stability of micelles as function of the ratio and distribution pattern of ionic and hydrophobic units in...
We report a combined experimental and theoretical study of micellization of block copolymer with hydrophilic nonionic corona‐forming blocks and weak polyelectrolyte (wPE) core‐forming blocks with pH‐triggered solubility in aqueous solutions. We demonstrate that in addition to micelles with neutral cores, there exist two other types of micelles with PE‐ or ionomer‐like cores, in which monovalent counterions...
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