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The following iron(II) complexes of 2,6‐bis(oxazolinyl)pyridine (PyBox; LH) derivatives are reported: [Fe(LH)2][ClO4]2 (1); [Fe((R)‐LMe)2][ClO4]2 ((R)‐2; LMe=2,6‐bis{4‐methyloxazolinyl}pyridine); [Fe((R)‐LPh)2][ClO4]2 ((R)‐3) and [Fe((R)‐LPh)((S)‐LPh)][ClO4]2 ((RS)‐3; LPh=2,6‐bis{4‐phenyloxazolinyl}pyridine); and [Fe((R)‐LiPr)2][ClO4]2 ((R)‐4) and [Fe((R)‐LiPr)((S)‐LiPr)][ClO4]2 ((RS)‐4; LiPr=2,6‐...
The cover image compares the molecular spin states of two diastereomers of a spin‐crossover iron(II) complex. Solution‐phase magnetic measurements show the low‐spin state of the heterochiral (meso) diastereomer is stabilized relative to its homochiral (rac) congener. This reflects a steric clash between phenyl substituents in the rac isomer, which occupies two diagonal quadrants in the molecule. The...
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