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Preferential oxidation of CO in H2 was studied by in situ ultraviolet–visible (UV–Vis) and mass spectrometry on flat model Cu and Cu/CeOx catalysts. The experimental findings were interpreted and compared with the results from density functional theory (DFT) calculations of the adsorption and activation energies for the essential reaction steps on Cu(1 1 1). It was found that oxidation of CO preferentially...
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