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Two families of lanthanide chlorides LnCl 3 L 2 (H 2 O) n and LnCl 3 L(H 2 O) m where L is 1,10-phenanthroline or 2,2′-bipyridine were synthesized. Their luminescence properties were investigated in the solid state and 1-dodecyl-3-methylimidazolium chloride solution. The structural peculiarities of lanthanide chlorides were elucidated by joint...
The convenient synthesis of a new macrocyclic octadentate chelate based on 2,2'-bipyridine chromophore and diethylenetriaminetriacetic acid core is described. In aqueous solutions, the corresponding Eu(III) and Tb(III) neutral complexes are kinetically inert and show very bright luminescence when excited with UV radiation (Φ=11 and 25% respectively). We also report the potentiality of these complexes...
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