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A new bis(pentadentate) pyrazole‐bridged proligand HLbis5 providing two {N5} binding pockets and its diruthenium complex [Lbis5Ru2(MeCN)2](PF6)3 (1) have been synthesized, and the structure of 1 has been elucidated by X‐ray diffraction. The two exogenous MeCN ligands in 1 are both directed into the central pocket created by the two metal ion compartments and interfere with each other, which leads...
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