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The effect of Rh‐ and Ir‐centers on the optical properties of the BODIPY core has been studied. To this end, novel metal complexes tethered to BODIPY have been prepared through an easy and versatile procedure using N‐directed C–H activation reactions. The organometallic moiety has a tremendous influence on the emissive properties of the BODIPY fragment. A photoinduced electron transfer (PET) mechanism...
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