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The self‐assembly of a Pd2L4 capsule consisting of Pd(II) ions and ditopic ligands comprising an anthracene panel takes place mainly through three pathways, as determined by QASAP (quantitative analysis of self‐assembly process). This differs substantially from the self‐assembly process of a geometrically similar Pd2L4 cage without anthracene panels, indicating that the interactions between the neighboring...
The effect of molecular interactions between the components on the self‐assembly process of Pd2L4 structures was investigated by a 1H NMR‐based quantitative approach (QASAP: quantitative analysis of self‐assembly process). Although the self‐assembly of the Pd2L4 cage without interactions between the bent ligands took place, mainly producing small intermediates, the self‐assembly of the Pd2L4 capsule...
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