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Goldenes Arin? Gold‐Arin‐Komplexe werden als Übergangszustände in dualen Gold‐katalysierte Cyclisierungen von cis‐Endiinen angenommen (siehe Schema; DCE=1,2‐Dichlorethan); sie werden besser beschrieben als ortho‐Aurophenyl‐Kationen, die mit schwachen Nucleophile reagieren und leichte intramolekulare Insertionen in C(sp3)‐H‐Bindungen eingehen. Mit der Methode wurden Indane, kondensierte Heteroarene...
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