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Vanadium–silver bimetallic oxide cluster ions (VxAgyOz+; x=1–4, y=1–4, z=3–11) are produced by laser ablation and reacted with ethane in a fast‐flow reactor. A reflectron time of flight (Re‐TOF) mass spectrometer is used to detect the cluster distribution before and after the reactions. Hydrogen atom abstraction (HAA) reactions are identified over VAgO3+, V2Ag2O6+, V2Ag4O7+, V3AgO8+, V3Ag3O9+, and...
Why so different? The comparison of the reaction of “bare” [P4O10].+ and [V4O10].+ with ethene by mass‐spectrometric and computational studies permits insight into mechanistic aspects of the competition between CH bond activation and oxygen‐atom and electron transfers. Whereas [P4O10].+ reacts by homolytic CH bond cleavage and electron transfer, the isostructural [V4O10].+ shows only oxygen‐atom...
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