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The reported immobilization strategy for the riboflavin photocatalyst as a lasso catching the catalyst is depicted in the frontispiece. The lasso is held by silica “cowboy” particles, and the sand of the desert reinforces the silica theme. The sun conveys that light irradiation is necessary for the isomerization reaction. For more information see the Communication by B. J. Ravoo, R. Gilmour, et al...
The covalent immobilization of the biomimetic, photo‐organocatalyst (−)‐riboflavin on silica micro‐ and nanoparticles via atom transfer radical polymerization (ATRP) is disclosed. Given the effectiveness of (−)‐riboflavin as a versatile, environmentally benign photocatalyst, an immobilization strategy based on acrylate‐linker modification of the catalyst core and controlled polymerization on initiator...
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