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Size and shape, in particular of the external surfaces, are very important factors in determining the photocatalytic activity of TiO2 nanostructures. Here, we demonstrate that the sea‐urchin‐like rutile superstructure with ultrathin nanorods and exposed {110} faces is an excellent photocatalyst in the removal of CrVI ions from plating wastewater. The superstructure consists of ultrathin rutile nanorods...
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