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Cyclic saturated aminosulfonyl fluorides were synthesized as their HCl salts. The compounds were found to be stable upon storage and could be used for the protecting‐group‐free synthesis of sulfonamides. In the presence of the −SO2F group, the nitrogen atom could be modified by means of acylation, arylation, or reductive amination to give products that have high potential for the synthesis of bioactive...
The cover picture shows a view of downtown Kyiv, the capital of Ukraine. There is a constellation of a novel scaffold for protecting‐free group synthesis of aliphatic sulfonamides in the sky. Cyclic aliphatic aminosulfonyl fluorides were developed as alternatives to unstable aminosulfonyl chlorides by scientists from Enamine (http://www.enamine.net) and ChemSpace (http://www.chem‐space.com). More...
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