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A bifunctional MOF for selective CO2 capture and efficient aqueous‐phase sensing of 2,4,6‐trinitrophenol (TNP) has been rationally designed and synthesized. Owing to the presence of basic (−NH2) functionalized pore surface, the MOF exhibits selective adsorption of CO2 with a high value of heat of adsorption (Qst = 46.5 kJ mol−1) which is about 10 kJ mol−1 higher than that of the analogues MOF without...
A bifunctional, microporous ZnII metal–organic framework, [Zn2(NH2BDC)2(dpNDI)]n (MOF1) (where, NH2BDC=2‐aminoterephthalic acid, dpNDI=N,N′‐di(4‐pyridyl)‐1,4,5,8‐naphthalenediimide) has been synthesized solvothermally. MOF1 shows an interesting two‐fold interpenetrated, 3D pillar‐layered framework structure composed of two types of 1D channels with dimensions of approximately 2.99×3.58 Å and 4.58×5...
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