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A simple system of epitaxial film electrodes with no additives is desirable for investigation surface reactions and anisotropic electrochemical properties of battery's active materials. In this work we demonstrate the possibility of growing epitaxially by pulsed laser deposition single orientation thin films of two phases, orthorhombic o-LiMnO2 and monoclinic m-Li2MnO3; the phases were and still are...
Epitaxial LiCoO2 (LCO) thin films of different orientations were fabricated by pulsed laser deposition (PLD) in order to model single-crystal behavior of intercalation cathodes during electrochemical reactions. This paper demonstrates that (1) epitaxial growth of LCO on a single crystal Nb-doped SrTiO3 (Nb:STO) of different orientations occurs with a single orientation relationship; (2) surface morphology...
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