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Using molecular dynamics simulation in combination with the embedded atom method we analyze the alloying reaction in Al-coated Ni nanoparticle with equi-atomic fractions and diameter of ∼4.5nm. The alloying reaction in the nanoparticle is accompanied by solid state amorphization of the Al-shell and Ni-core in the vicinity of the interface region. The large driving force for alloying of Ni and Al promotes...
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