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The synthesis of enantiomerically pure Ir(III) complexes with one or two BODIPY moieties has been achieved through the enantioselective C–H insertion from homochiral triazolium salts, containing a sulfoxide functionality in their structures. These homochiral salts were prepared by the sequential Cu‐catalyzed alkyne‐azide cycloaddition (CuAAC) of an azide and one alkynyl sulfoxide, followed by a Suzuki...
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