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This paper presents results of research on modeling of a coal structure and sorption system properties. Investigations combine a viewpoint on surface heterogeneity, coming from approach aimed at adsorption mechanism identification, when applied to real coal structure in multiple sorption model (MSM) simulations. For imaging of surface heterogeneity in real coal structure two hypothetical models are...
The subject of the article is the thermodynamic analysis of the sorption of aliphatic hydrocarbons in hard coals from polish mines. The analysis is based on a Multisorption model designed for describing small molecule sorption in different types of carbonaceous materials (e.g. hard coals, lignites or active carbons). Experimental isotherms of hydrocarbons: hexane, heptane, octane and benzene, in hard...
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