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The effect of sulphur poisoning on the activity and selectivity in the Fischer–Tropsch synthesis of a Co/γ-Al 2 O 3 catalyst, investigated in a previous work under conditions relevant to industrial operation, has been described in this work by means of a complete kinetic model, able to predict at the same time the CO conversion and the product distribution (paraffins and olefins from...
A global kinetic model of the FTS over a Co/Al2O3 state-of-the-art catalyst is developed in a fixed bed micro-reactor under conditions relevant to industrial operation (temperature, 210–235°C; pressure, 8–25bar; H2/CO feed molar ratio, 1.8–2.7; gas hourly space velocity, 2000–7000cm3(STP)/h/gcatalyst). On the basis of proposed reaction mechanisms, developed according to the carbide theory and the...
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