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Ein Kampf der Bindungen:Silicium(II)‐ und Nickel(0)‐Atome in einem Komplex vereint können die extrem starken B‐O‐Bindungen von Catecholboran, HB(cat), brechen und liefern so den ersten isolierbaren Hydroborylennickel‐Komplex, dessen blaue Farbe den Himmel im Bild füllt. In der Zuschrift auf S. 7578 ff. beschreiben M. Driess et al. die Synthese und die neuartige Reaktivität eines acyclischen Silylennickel(0)‐Komplexes,...
The first 16 valence electron [bis(NHC)](silylene)Ni0 complex 1, [(TMSL)ClSi:→Ni(NHC)2], bearing the acyclic amido‐chlorosilylene (TMSL)ClSi: (TMSL=N(SiMe3)Dipp; Dipp=2,6‐Pri2C6H4) and two NHC ligands (N‐heterocyclic carbene=:C[(Pri)NC(Me)]2) was synthesized in high yield and structurally characterized. Compound 1 is capable of facile dihydrogen activation under ambient conditions to give the corresponding...
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