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The effect of solvents in the 'vapor-phase' Beckmann rearrangement of cyclohexanone oxime was studied on silicalite-1 catalyst through kinetic measurements. Solvents with various polarities were examined for the reaction. It was found that ethanol, which has medium polarity, was effective in the formation of -caprolactam. The rate of -caprolactam formation fitted the Langmuir-type rate equation...
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