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The Meinwald rearrangement is a synthetically useful reaction but often lacks regioselectivity and stereocontrol. A significant challenge in the Meinwald rearrangement of internal epoxides is the non‐regioselective migration of different substituents to give a mixture of products. Herein, an enzyme‐catalyzed regioselective and stereospecific 1,2‐methyl shift in the Meinwald rearrangement of internal...
The Meinwald rearrangement is a synthetically useful reaction but often lacks regioselectivity and stereocontrol. A significant challenge in the Meinwald rearrangement of internal epoxides is the non‐regioselective migration of different substituents to give a mixture of products. Herein, an enzyme‐catalyzed regioselective and stereospecific 1,2‐methyl shift in the Meinwald rearrangement of internal...
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