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The acceptorless dehydrogenation of methanol to carbon monoxide and hydrogen was investigated using homogeneous molecular complexes. Complexes of ruthenium and manganese comprising the MACHO ligand framework showed promising activities for this reaction. The molecular ruthenium complex [RuH(CO)(BH4)(HN(C2H4PPh2)2)] (Ru‐MACHO‐BH) achieved up to 3150 turnovers for carbon monoxide and 9230 turnovers...
The acceptorless dehydrogenation of methanol to carbon monoxide and hydrogen was investigated using homogeneous molecular complexes. Complexes of ruthenium and manganese comprising the MACHO ligand framework showed promising activities for this reaction. The molecular ruthenium complex [RuH(CO)(BH4)(HN(C2H4PPh2)2)] (Ru‐MACHO‐BH) achieved up to 3150 turnovers for carbon monoxide and 9230 turnovers...
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