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By using density functional theory (DFT)-B3LYP method, the mechanism and energetics of the addition reactions of H2O to germastannenes (H2Ge=SnH2 and Ph2Ge=SnPh2) have been theoretically studied. The computed results show that the monomer, dimer and trimer of H2O are all likely reagents towards germastannenes. All reactions start from formation of the initial nucleophilic or electrophilic complexes...
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